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Chapter 14 APPLICATION OF ULTRAVIOLET/VISIBLE MOLECULAR ABSORPTION SPECTROMETRY - page 10 / 33

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n * Transitions

Saturated compounds containing atoms with unshared electrons are capable of n * transitions. These transitions require less energy than the * type and can be brought about by radiation in the region of between 150 and 250 nm, with most absorption peaks appearing below 200 nm. The molar absorptivities are low to intermediate in magnitude and range between 100 and 3000 L cm-1 mol -1.

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