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Chapter 14 APPLICATION OF ULTRAVIOLET/VISIBLE MOLECULAR ABSORPTION SPECTROMETRY - page 16 / 33

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Absorption Involving d and f Electrons

Most transition-metal ions absorb in the ultraviolet or visible region of the spectrum. For the lanthanide and actinide series, the absorption process results from electronic transition of 4f and 5f electrons; for elements of the first and second transition-metal series, the 3d and 4d electrons are responsible.

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