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Chapter 14 APPLICATION OF ULTRAVIOLET/VISIBLE MOLECULAR ABSORPTION SPECTROMETRY - page 2 / 33

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THE MAGNITUDE OF MOLAR ABSORPTIVITIES

Molar absorptivities range from zero up to a maximum on the order of 105 are observed. The magnitude of depends upon the probability for an energy-absorbing transition to occur. Peaks having molar absorptivities less than about 103 are classified as being of low intensity. They result from so-called forbidden transitions, which have probabilities of occurrence that are less than 0.01.

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