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Chapter 14 APPLICATION OF ULTRAVIOLET/VISIBLE MOLECULAR ABSORPTION SPECTROMETRY - page 20 / 33

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Absorption by Elements of the First and

Second Transition-Metal Series

The ions and complexes of the first two transition series tend to absorb visible radiation in one if not all of their oxidation states. The absorption bands are often broad and are strongly influenced by chemical environmental factors. The spectral characteristics of transition metals involve electronic transitions among the various energy levels of d orbitals.

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