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Chapter 14 APPLICATION OF ULTRAVIOLET/VISIBLE MOLECULAR ABSORPTION SPECTROMETRY - page 5 / 33

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Types of Absorbing Electrons

The electrons that contribute to absorption by a molecule are: (1) those that participate directly in bond formation between atoms; (2) nonbonding or unshared outer electrons that are largely localized about such atoms as oxygen, the halogens, sulfur, and nitrogen. The molecular orbitals associated with single bonds are designated as sigma () orbitals, and the corresponding electrons are electrons.

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