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The Supramolecular Chemistry Chemistry of Non-covalent Interactions: Host-guest Complexes - page 18 / 39

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Confirming Results With a Model Compound

R= -NH-Ph

Association constants with anions are almost the same

 for this model as well as the original host.

In the case of Benzoate there is a large change from

 1800 to 161000!

If R= Ph ( i.e. amide instead of urea the Kf drops significantly.

model

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