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The Supramolecular Chemistry Chemistry of Non-covalent Interactions: Host-guest Complexes - page 32 / 39

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Cyclic Voltammetry

After addition of crown ether

 0.0   0.2   0.3

Cyclic voltammogram for Ru(II) complex

E/volt

20

Change in diagram after addition of crown ether is an evidence for binding.

 reversibe

negative shift of E 1/2 shows that Ru(III) makes a more stable adduct with the crown ether

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